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<dc:creator>Vallejos Calzada, Saúl</dc:creator>
<dc:creator>Muñoz Santamaría, María Asunción</dc:creator>
<dc:creator>Ibeas Cortes, Saturnino</dc:creator>
<dc:creator>Serna Arenas, Felipe</dc:creator>
<dc:creator>García García, Félix Clemente</dc:creator>
<dc:creator>García Pérez, José Miguel</dc:creator>
<dc:date>2015-01</dc:date>
<dc:description>Selective and sensitive solid sensory substrates for detecting Al(III) in pure&#xd;
water are reported. The material is a flexible polymer film that can be handled and exhibits gel&#xd;
behavior and membrane performance. The film features a chemically anchored salicylaldehyde&#xd;
benzoylhydrazone derivative as an aluminum ion fluorescence sensor. A novel procedure for&#xd;
measuring Al(III) at the ppb level using a single solution drop in 20 min was developed. In this&#xd;
procedure, a drop was allowed to enter the hydrophilic material for 15 min before a 5 min&#xd;
drying period. The process forced the Al(III) to interact with the sensory motifs within the&#xd;
membrane before measuring the fluorescence of the system. The limit of detection of Al(III)&#xd;
was 22 ppm. Furthermore, a water-soluble sensory polymer containing the same sensory&#xd;
motifs was developed with a limit of detection of Al(III) of 1.5 ppb, which was significantly&#xd;
lower than the Environmental Protection Agency recommendations for drinking water.</dc:description>
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<dc:identifier>http://hdl.handle.net/10259/4325</dc:identifier>
<dc:language>eng</dc:language>
<dc:publisher>American Chemical Society</dc:publisher>
<dc:title>Forced Solid-State Interactions for the Selective “Turn-On” Fluorescence Sensing of Aluminum Ions in Water Using a Sensory Polymer Substrate</dc:title>
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