2026-05-07T02:52:54Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/43362022-04-29T12:02:46Zcom_10259_4244com_10259_5086com_10259_2604col_10259_4245

García Solaesa, Ángela Bucio López, Silvia Liliana Sanz Díez, Mª Teresa Beltrán Calvo, Sagrario Rebolleda Alonso, Sara 2017-02-13T09:28:27Z 2017-02-13T09:28:27Z 2013-10 0378-3812 http://hdl.handle.net/10259/4336 Monoacylglycerols (MAGs) can be produced by lipase-catalyzed glycerolysis of oils and fats at atmospheric pressure and low temperature. The use of organic solvents as reaction media helps to create a homogeneous reaction system between the immiscible reactants glycerol and oil. In this work liquid–liquid equilibrium at two different temperatures (303.2 and 323.2 K) and at atmospheric pressure has been determined for two solvent-systems in the glycerolysis of fish oil (sardine oil): glycerol + sardine oil + tert-butanol and glycerol + sardine oil + tert-pentanol. From the experimental solubility (binodal) curves and tie-lines, it could be observed that the system mutual solubility does not significantly increase by increasing temperature from 303.2 to 323.2 K. The Othmer–Tobias correlation was used to analyze the consistency of the tie-line data. The experimental liquid–liquid data were correlated satisfactorily by using the NRTL model for the activity coefficient calculation. MINECO (CTQ2012-39131-C02-01) and CDTI (Ref. IDI-20111225) application/pdf eng Elsevier Fluid Phase Equilibria. 2013, V. 356, 25 October 2013, Pages 284–290 http://dx.doi.org/10.1016/j.fluid.2013.07.026 Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Liquid–liquid equilibria Fish oil Glycerolysis Tertiary alcohols Chemical engineering Ingeniería química Liquid–liquid equilibria for systems glycerol + sardine oil + tert-alcohols info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion