2026-05-07T05:22:06Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/45282021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597
Repositorio Institucional de la Universidad de Burgos
author
Rubio Presa, Rubén
author
Fernández Rodríguez, Manuel A.
author
Pedrosa Sáez, María de los Remedios
author
Arnáiz García, Francisco Javier
author
Sanz Díez, Roberto
2017-07-13T09:28:47Z
2018-05-17T02:45:07Z
2017-05
1615-4150
http://hdl.handle.net/10259/4528
10.1002/adsc.201700071
A molybdenum-catalyzed deoxygenationof pyridine N -oxides and N-hydroxybenzotriazoles,as well as other azole N-oxides, has been developedusing pinacol as an environmentally friendly oxo-acceptor. The only by-products are acetone andwater making the process a convenient alternativeto established protocols in terms of waste gener-ation. The reaction is highly chemose lective and avariety of functional groups are tolerated. Theprocesses are usually very clean allowing theisolation of the pure deoxygenated products after asimple extraction in most cases.
eng
amine N-oxides
deoxygenation
molyb-denum
microwave heating
N-hydroxybenzotria-zoles
Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent
info:eu-repo/semantics/article
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URL
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https://riubu.ubu.es/bitstream/10259/4528/3/Rubio-ASC_2017.pdf.txt
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Rubio-ASC_2017.pdf.txt