2026-04-27T21:10:12Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/47832024-06-12T11:48:08Zcom_10259_4323com_10259_5086com_10259_2604col_10259_4330

Alcalde García, Rafael T. 14 500 0000-0002-5611-220X Atilhan, Mert 51023856-6e72-4667-b27a-fe52e5115d61 600 Aparicio Martínez, Santiago 30 500 0000-0001-9996-2426 2018-05-15T09:38:39Z 2018-05 2020-05 0167-7322 http://hdl.handle.net/10259/4783 10.1016/j.molliq.2018.02.064 The characteristics of intermolecular forces in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide + ethanol mixtures were studied in the full composition range using a combined experimental and theoretical approach. Molecular clusters were used to model the short-range interactions between the ionic liquid and the primary alcohol, studied using density functional theory calculations, inferring preferred interaction sites, strength of interactions and topological characteristics of intermolecular forces. Dynamic viscosity and refraction index were measured as a function of mixture composition and temperature and analysed in terms of evolution of intermolecular forces. Raman IR studies were carried out and the analysis of selected spectral regions allowed to characterize hydrogen bonding evolution for all the possible interacting sites. Junta de Castilla y León (Spain, project BU324U14) application/pdf eng Elsevier Journal of Molecular Liquids. 2018, V. 258, p. 1-9 https://doi.org/10.1016/j.molliq.2018.02.064 https://doi.org/10.1016/j.molliq.2018.02.064 10.1016/j.molliq.2018.02.064 info:eu-repo/grantAgreement/JCyL/BU324U14 Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Ionic liquid Imidazolium Molecular solvent Mixtures DFT Raman Hydrogen bonding Chemistry, Physical and theoretical Química física Intermolecular forces in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide + ethanol mixtures info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion CC-LICENSE license_rdf license_rdf application/rdf+xml; charset=utf-8 805 https://riubu.ubu.es/bitstream/10259/4783/8/license_rdf 4460e5956bc1d1639be9ae6146a50347 MD5 8 THUMBNAIL Alcalde-JML_2018.pdf.jpg Alcalde-JML_2018.pdf.jpg IM Thumbnail image/jpeg 4328 https://riubu.ubu.es/bitstream/10259/4783/7/Alcalde-JML_2018.pdf.jpg e27a4aec8ce88be8de8d6eb69caf318d MD5 7 ORIGINAL Alcalde-JML_2018.pdf Alcalde-JML_2018.pdf application/pdf 1471814 https://riubu.ubu.es/bitstream/10259/4783/1/Alcalde-JML_2018.pdf c294a725dbca04678a62c4837010b334 MD5 1 LICENSE license.txt license.txt text/plain; charset=utf-8 998 https://riubu.ubu.es/bitstream/10259/4783/5/license.txt aa90105e1c90a1b4fe810649aa967b7d MD5 5 TEXT Alcalde-JML_2018.pdf.txt Alcalde-JML_2018.pdf.txt Extracted text text/plain 51545 https://riubu.ubu.es/bitstream/10259/4783/6/Alcalde-JML_2018.pdf.txt 7ff2a7463a8e43fb929290e12d917b2b MD5 6 10259/4783 oai:riubu.ubu.es:10259/4783 2024-06-12 13:48:08.656 Repositorio Institucional de la Universidad de Burgos bubrep@ubu.es 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