2026-06-17T21:16:57Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/49202021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

Virumbrales, Cintia Suarez Pantiga, Samuel Solas Luera, Marta Fernández Rodríguez, Manuel A. Sanz Díez, Roberto 2018-09-07T08:21:18Z 2019-04-21T02:45:07Z 2018-04 1477-0520 http://hdl.handle.net/10259/4920 10.1039/c8ob00406d The gold(I)-catalyzed oxycyclization of β-aryl monosubstituted o-(alkynyl)styrenes gives rise to 1-α-methoxy or 1-α-hydroxybenzyl- 1H-indenes in a diastereospecific way. In contrast to β,β-disubstituted o-(alkynyl)styrenes, the stereochemical outcome of this process, diastereospecific reaction supports the higher contribution of a gold intermediate with a cyclopropylcarbene-like character. eng info:eu-repo/semantics/openAccess Gold(I)-catalyzed diastereoselective synthesis of 1-α-oxybenzyl-1H-indenes info:eu-repo/semantics/article