2026-06-21T21:55:18Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/49232021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
Repositorio Institucional de la Universidad de Burgos
author
Velasco Pérez, Noelia
author
Virumbrales, Cintia
author
Sanz Díez, Roberto
author
Suarez Pantiga, Samuel
author
Fernández Rodríguez, Manuel A.
2018-09-07T09:53:26Z
2019-05-18T02:45:07Z
2018-05
1523-7060
http://hdl.handle.net/10259/4923
10.1021/acs.orglett.8b00854
The cross-coupling reaction of alkenyl bromides with thiols catalyzed by palladium complexes derived from inexpensive dppf ligand is reported. These reactions occur under low catalyst loading and in high yields and display wide scope, including the coupling of bulky thiols and trisubstituted bromoolefins, and functional group tolerance. In addition, the thioetherification of less reactive chloroalkenes and, for the first time, alkenyl tosylates was accomplished using a catalyst generated from CyPFtBu alkylbisphosphine ligand.
eng
General synthesis of alkenyl sulfides by palladium-catalyzed thioetherification of alkenyl halides and tosylates
info:eu-repo/semantics/article
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URL
https://riubu.ubu.es/bitstream/10259/4923/1/Velasco-ol_2018.pdf
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Velasco-ol_2018.pdf
URL
https://riubu.ubu.es/bitstream/10259/4923/3/Velasco-ol_2018.pdf.txt
File
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Velasco-ol_2018.pdf.txt