2026-04-27T14:20:47Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/49232021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
Velasco Pérez, Noelia
572
500
Virumbrales, Cintia
578
500
0000-0003-0211-8988
Sanz Díez, Roberto
531
500
Suarez Pantiga, Samuel
544
500
Fernández Rodríguez, Manuel A.
174
500
2018-09-07T09:53:26Z
2019-05-18T02:45:07Z
2018-05
1523-7060
http://hdl.handle.net/10259/4923
10.1021/acs.orglett.8b00854
The cross-coupling reaction of alkenyl bromides with thiols catalyzed by palladium complexes derived from inexpensive dppf ligand is reported. These reactions occur under low catalyst loading and in high yields and display wide scope, including the coupling of bulky thiols and trisubstituted bromoolefins, and functional group tolerance. In addition, the thioetherification of less reactive chloroalkenes and, for the first time, alkenyl tosylates was accomplished using a catalyst generated from CyPFtBu alkylbisphosphine ligand.
Junta de Castilla y León and FEDER
(BU076U16) and Ministerio de Economía
y Competitividad
(MINECO) and FEDER (CTQ2016-75023-C2-1-P)
application/pdf
eng
American Chemical Society
Organic Letters. 2018, V. 20, n. 10, p. 2848-2852
https://doi.org/10.1021/acs.orglett.8b00854
info:eu-repo/grantAgreement/JCyL/BU076U16
info:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-1-P
Química orgánica
Chemistry, Organic
General synthesis of alkenyl sulfides by palladium-catalyzed thioetherification of alkenyl halides and tosylates
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
info:eu-repo/semantics/openAccess
THUMBNAIL
Velasco-ol_2018.pdf.jpg
Velasco-ol_2018.pdf.jpg
IM Thumbnail
image/jpeg
4840
https://riubu.ubu.es/bitstream/10259/4923/4/Velasco-ol_2018.pdf.jpg
ace210f11b97feaecd8e7937051fdf90
MD5
4
ORIGINAL
Velasco-ol_2018.pdf
Velasco-ol_2018.pdf
application/pdf
827347
https://riubu.ubu.es/bitstream/10259/4923/1/Velasco-ol_2018.pdf
155a7a282f945936fc9036496270432c
MD5
1
LICENSE
license.txt
license.txt
text/plain; charset=utf-8
999
https://riubu.ubu.es/bitstream/10259/4923/2/license.txt
b295bcbce42e2caabeb0c623d3860c06
MD5
2
TEXT
Velasco-ol_2018.pdf.txt
Velasco-ol_2018.pdf.txt
Extracted text
text/plain
25294
https://riubu.ubu.es/bitstream/10259/4923/3/Velasco-ol_2018.pdf.txt
a1f3839579dde819403e049401f8a249
MD5
3
10259/4923
oai:riubu.ubu.es:10259/4923
2021-11-10 10:38:25.18
Repositorio Institucional de la Universidad de Burgos
bubrep@ubu.es
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