2026-05-30T08:59:30Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/49272024-11-05T11:08:09Zcom_10259_4393com_10259_5086com_10259_2604col_10259_4394
Repositorio Institucional de la Universidad de Burgos
author
Cobos, Ana .
author
González López, Juan Antonio
author
Hevia de los Mozos, Fernando
author
García de la Fuente, Isaías
author
Alonso Tristán, Cristina
2018-09-07T11:17:49Z
2017-12
0167-7322
http://hdl.handle.net/10259/4927
Data on density, ρ, speed of sound, c, and refractive index, nD, have been reported at (293–303.15) K for the N,N-dimethylacetamide (DMA) + CH3CO(CH2)u − 1CH3 (u = 1, 2, 3) systems, and at 298.15 K for the mixture with u = 5. These data have been used to compute excess molar volumes, VmE, excess adiabatic compressibilities, κSE, and excess speeds of sound cE. Negative VmE values indicate the existence of structural effects and interactions between unlike molecules. From molar excess enthalpies, HmE, available in the literature for N,N-dimethylformamide (DMF), or N-methylpyrrolidone (NMP) + n-alkanone systems, it is shown: (i) amide-ketone interactions are stronger in DMF systems than in those with NMP; (ii) they become weaker when u increases in mixtures with a given amide. Structural effects largely contribute toHmE and are more relevant in mixtures containing NMP. The application of the Flory's model reveals that the random mixing hypothesis is valid in large extent for DMF solutions, while NMP systems are characterized by rather strong orientational effects. From values of molar refraction and of the product PintVm (where Pint is the internal pressure and Vm the molar volume), it is concluded that dispersive interactions increase with u, or when DMF is replaced by DMA in mixtures with a fixed ketone.
eng
Attribution-NonCommercial-NoDerivatives 4.0 International
Amides
n-Alkanones
Thermophysical properties
Flory
Random mixing
Thermodynamics of amide + ketone mixtures. 2. Volumetric, speed of sound and refractive index data for N,N-dimethylacetamide + 2-alkanone systems at several temperatures. Application of Flory's model to tertiary amide + n-alkanone systems
info:eu-repo/semantics/article
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https://riubu.ubu.es/bitstream/10259/4927/6/Cobos-jmql_2017.pdf.txt
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Cobos-jmql_2017.pdf.txt