2026-10-21T21:03:00Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/50562024-07-24T11:42:11Zcom_10259_9476com_10259.4_106com_10259_2604col_10259_9477

Senes, Nina . Iacomini, Antonio . Domingo, Neus . Enzo, Stefano Mulas, Gabriele Cuesta López, Santiago Garroni, Sebastiano 2019-02-05T10:06:56Z 2018-08 1862-6300 http://hdl.handle.net/10259/5056 10.1002/pssa.201700921 Due to the ever‐increasing restrictions connected to the use of toxic lead‐based materials, the developing of lead‐free piezoceramics has become one of the most urgent tasks. In this context, potassium sodium niobate materials (KNN) have attracted a lot of interest as promising candidates due to their excellent piezo properties. For this reason, many efforts have been addressed to optimize the synthesis process now suffering by several drawbacks including the high volatilization of potassium and sodium at the conventional high temperature treatments and the use of expensive metal precursors. To overcome these issues, a new modified Pechini method to synthesize single phase K0.5Na0.5NbO3 powders, from water soluble metal precursors, is presented. Microstructural and structural parameters are characterized by X‐ray diffraction (XRD). Depending on the amount of citric acid added to the starting reagents, two pure single‐phase K0.5Na0.5NbO3 (2 g citric acid) and K0.3Na0.7NbO3 (0.2 g citric acid), respectively, are obtained with a good crystallinity at a moderate temperature of 500 °C. The piezo responses of the as calcined systems are tested by piezoresponse force microscopy (PFM). K0.5Na0.5NbO3 exhibits a much higher response with respect to the other phase, which relates to the larger crystallinity and to the chemical composition. H2020-MSCA-IF-2015 grantnumber #70795. panishMinisterio de Economía y Competitividad (MINECO) under projectFIS2015-73932-JIN. ICN2 acknowledges support from the Severo OchoaProgram (MINECO, Grant No. SEV-2013-0295 application/pdf eng Wiley Physica status solidi (a). 2018, V. 215, n. 16, 1700921 https://doi.org/10.1002/pssa.201700921 info:eu-repo/grantAgreement/EC/H2020/70795 info:eu-repo/grantAgreement/MINECO/FIS2015‐73932‐JIN info:eu-repo/grantAgreement/MINECO/SEV-2013-029 modified‐pechini method ead-free piezoceramics piezoresponse forcemicroscop potassium sodium niobate X-ray diffraction Física Physics Local Piezoelectric Behavior of Potassium Sodium Niobate Prepared by a Facile Synthesis via Water Soluble Precursors info:eu-repo/semantics/article info:eu-repo/semantics/submittedVersion info:eu-repo/semantics/openAccess