2026-07-29T05:16:25Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/53362022-04-08T07:44:09Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845

Hernández Muñoz, Sheila Perales Rondon, Juan Víctor Heras Vidaurre, Aránzazu Colina Santamaría, Álvaro Spectroelectrochemistry Electrochemistry Raman EC-SOERS In this work, a new and easy methodology to determine uric acid in relevant samples using Raman spectroelectrochemistry is presented. The spectroelectrochemistry experiment is based on the in-situ formation of a suitable substrate that enables the enhancement of the Raman signal of an analyte during the oxidation stage of a silver electrode. This phenomenon is known as electrochemical surface oxidation enhanced Raman scattering (EC-SOERS) and has proved to be useful in quantitative analysis using disposable screen printed electrodes. The successful combination of EC-SOERS with PARAFAC analysis allows the determination of uric acid in a relevant complex sample avoiding the use of standard addition method and without using a baseline correction, which simplifies the application of such methodology in routine analysis. 2020-06-10 2020-06-10 2019-11 info:eu-repo/semantics/article 0003-2670 http://hdl.handle.net/10259/5336 10.1016/j.aca.2019.07.057 eng Analytica Chimica Acta. 2019, V. 1085, p. 61-67 https://doi.org/10.1016/j.aca.2019.07.057 info:eu-repo/grantAgreement/MINECO/CTQ2017-83935-R info:eu-repo/grantAgreement/JCyL/BU297P18 http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Attribution-NonCommercial-NoDerivatives 4.0 Internacional Elsevier