2026-04-28T18:31:52Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/53462022-04-08T10:27:10Zcom_10259_4376com_10259_5086com_10259_2604col_10259_4377
Cunha Silva, Hugo
1
500
Arcos Martínez, Julia
36
500
0000-0002-4932-6445
2020-06-17T13:46:47Z
2020-06-17T13:46:47Z
2019-03
0925-4005
http://hdl.handle.net/10259/5346
10.1016/j.snb.2018.11.108
The demand for bromide determination has increased over recent years. Sources of bromide contamination can be found in brines from hydraulic fracturing, pesticides and brominated polymers. Widely used in different applications, the bromide anion is present in the composition of several compounds. In this paper, we present a new selective voltammetric method for bromide determination, based on a screen-printed carbon electrode (SPCE) modified with rhodium nanoparticles (Rh-Nps), that is used as a sensing platform. The modification of the electrode surface with Rh-Nps and the presence of chloride in the sample, improved device performance, increasing the sensitivity of the Rh/SPCE-based sensor for bromide determination. The proposed sensor is simple to manufacture, easy to operate, and it offers a fast and accurate analysis. A single drop of the sample on the sensor is sufficient for the determination of bromide through measurement of voltammetric cathodic peaks, generated after a previous anodic stripping step. This disposable sensor offers a detection limit of 39 μM, with a calibration range up to 40 mM, and a sensitivity of 23.28 μA/mM. Its application to real-life samples evidenced recovery values close to 100%, demonstrating the powerful analytical performance of the proposed method.
Spanish Ministry of Science and Innovation (MICINN), Ministry of Economy and Competitiveness (MINECO) and the European Regional Development Fund (FEDER) (TEC20013-40561-P and MUSSEL RTC-2015-4077-2). Hugo Cunha-Silva would like to acknowledge funding from the Spanish Ministry of Economy (BES-2014-068214)
application/pdf
eng
Elsevier
Sensors and Actuators B: Chemical. 2019, V. 282, p. 603-608
https://doi.org/10.1016/j.snb.2018.11.108
info:eu-repo/grantAgreement/MINECO/MUSSEL RTC-2015-4077-2
info:eu-repo/grantAgreement/MICINN/TEC20013-40561-P
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
Bromide
Rhodium nanoparticles
Cathodic stripping voltammetry
Screen-printed electrod
Química analítica
Chemistry, Analytic
A disposable rhodium nanoparticle-modified screen-printed sensor for direct determination of bromide anions
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
Sensors and Actuators B: Chemical
282
603
608
TEXT
Cunha-sabc_2019.pdf.txt
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oai:riubu.ubu.es:10259/5346
2022-04-08 12:27:10.586
Repositorio Institucional de la Universidad de Burgos
bubrep@ubu.es
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