2026-06-18T01:07:04Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/55462021-11-06T23:42:16Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
Milián, Ana
García García, Patricia
Pérez Redondo, Adrián
Sanz Díez, Roberto
Vaquero, Juan J.
Fernández Rodríguez, Manuel A.
2020-11-10T08:58:49Z
2020-11-10T08:58:49Z
2020-11
1523-7060
http://hdl.handle.net/10259/5546
10.1021/acs.orglett.0c03067
1523-7052
Readily available o′-alkenyl-o-alkynylbiaryls, a particular
type of 1,7-enynes, undergo a selective cycloisomerization reaction in
the presence of a gold(I) catalyst to give interesting phenanthrene and
dihydrophenanthrene derivatives in high yields. The solvent used
provokes a switch in the evolution of the gold intermediate and plays a
key role in the reaction outcome.
Ministerio de Economıá y Competitividad (MINECO), AEI and FEDER (projects CTQ2017- 85263-R and CTQ2016-75023-C2-1-P), Instituto de Salud Carlos III (FEDER funds, ISCIII RETIC REDINREN RD16/ 0009/0015), Junta de Castilla y León and FEDER (BU291P18), and University of Alcalá (projects CCGP2017- EXP/016 and CCG2018/EXP-008
application/pdf
eng
American Chemical Society
Organic Letters. 2020, V. 22, n. 21, p. 8464–8469
https://doi.org/10.1021/acs.orglett.0c03067
info:eu-repo/grantAgreement/MINECO/CTQ2017- 85263-R
info:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-1-P
info:eu-repo/grantAgreement/JCyL/BU291P18
info:eu-repo/grantAgreement/Instituto de Salud Carlos III/RD16/ 0009/0015
info:eu-repo/grantAgreement/UAH/CCGP2017- EXP/016
info:eu-repo/grantAgreement/UAH/CCG2018/EXP-008
Hydrocarbons
Catalysts
Isomerization
Aromatic compounds
Solvents
Química orgánica
Chemistry, Organic
Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
info:eu-repo/semantics/openAccess
Organic Letters
22
21
8464
8469