2026-06-17T23:34:18Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/55462021-11-06T23:42:16Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

00925njm 22002777a 4500 dc Milián, Ana author García García, Patricia author Pérez Redondo, Adrián author Sanz Díez, Roberto author Vaquero, Juan J. author Fernández Rodríguez, Manuel A. author 2020-11 Readily available o′-alkenyl-o-alkynylbiaryls, a particular type of 1,7-enynes, undergo a selective cycloisomerization reaction in the presence of a gold(I) catalyst to give interesting phenanthrene and dihydrophenanthrene derivatives in high yields. The solvent used provokes a switch in the evolution of the gold intermediate and plays a key role in the reaction outcome. 1523-7060 http://hdl.handle.net/10259/5546 10.1021/acs.orglett.0c03067 1523-7052 Hydrocarbons Catalysts Isomerization Aromatic compounds Solvents Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes