2026-10-23T19:35:44Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/61202022-11-11T13:15:07Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845

Heras Vidaurre, Aránzazu Vulcano, Fabio Garoz Ruiz, Jesús Porcelli, Nicola Terzi, Fabio Colina Santamaría, Álvaro Seeber, Renato Zanardi, Chiara 2021-11-08T12:21:21Z 2021-11-08T12:21:21Z 2019-02 1424-8220 http://hdl.handle.net/10259/6120 10.3390/s19030518 A flexible electrode system entirely constituted by single-walled carbon nanotubes (SWCNTs) has been proposed as the sensor platform for -nicotinamide adenine dinucleotide (NADH) detection. The performance of the device, in terms of potential at which the electrochemical process takes place, significantly improves by electrochemical functionalization of the carbon-based material with a molecule possessing an o-hydroquinone residue, namely caffeic acid. Both the processes of SWCNT functionalization and NADH detection have been studied by combining electrochemical and spectroelectrochemical experiments, in order to achieve direct evidence of the electrode modification by the organic residues and to study the electrocatalytic activity of the resulting material in respect to functional groups present at the electrode/solution interface. Electrochemical measurements performed at the fixed potential of +0.30 V let us envision the possible use of the device as an amperometric sensor for NADH detection. Spectroelectrochemistry also demonstrates the effectiveness of the device in acting as a voltabsorptometric sensor for the detection of this same analyte by exploiting this different transduction mechanism, potentially less prone to the possible presence of interfering species. FEDER and both the Spanish Ministerio de Economía y Competitividad (Grants CTQ2017-83935-R-AEI/FEDER-UE) and the Consejería de Educación -Junta de Castilla y León- (Grant BU297P18). Jesus Garoz-Ruiz thanks Ministerio de Economía y Competitividad for his postdoctoral contracts (CTQ2014-55583-R; CTQ2017-83935-R AEI/FEDER-UE). Fabio Vulcano thanks the ISOF institute of CNR for supporting his PhD Grant. Nicola Porcelli thanks Università di Modena e Reggio Emilia for supporting his stay at the University of Burgos. application/pdf eng MDPI Sensors. 2019, V. 19, n. 3, 518 https://doi.org/10.3390/s19030518 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-83935-R/ES/ESPECTROELECTROQUIMICA RAMAN CUANTITATIVA info:eu-repo/grantAgreement/MINECO//CTQ2014-55583-R/ES/ESPECTROELETROQUIMICA MULTIFUNCIONAL: DESARROLLO DE SENSORES PARA ANALISIS IN SITU info:eu-repo/grantAgreement/Junta de Castilla y León//BU297P18 Atribución 4.0 Internacional http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess Single-walled carbon nanotubes Caffeic acid Catechol NADH oxidation Electrocatalysis Amperometric sensor Voltabsorptometric sensor Spectroelectrochemistry Química analítica Chemistry, Analytic A Flexible Platform of Electrochemically Functionalized Carbon Nanotubes for NADH Sensors info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion