2026-05-30T13:45:53Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/61272022-11-15T13:07:57Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845

00925njm 22002777a 4500 dc Hernández Muñoz, Sheila author Perales Rondon, Juan Víctor author Heras Vidaurre, Aránzazu author Colina Santamaría, Álvaro author 2021-06 Electrochemical Surface Oxidation Enhanced Raman Scattering (EC-SOERS) is a new phenomenon that provokes the enhancement of the Raman signal during the oxidation of a metal surface. Studies carried out so far indicate that carbonyl and carboxyl group are necessary to observe this phenomenon with a delocated charge being an important factor. In this work, the enhancement factors of EC-SOERS for different molecules, which present highly delocated charge and a carboxyl group, have been assessed. The systematic study of the enhancement factors helps to shed more light on the interaction of the molecules with the electrochemically generated SOERS substrates, yielding key information about the properties and specific features of this intriguing phenomenon. For the first time, a systematic information about the enhancement factors of this phenomenon is obtained. Analytical enhancement factors higher than 105 are obtained. 0013-4686 http://hdl.handle.net/10259/6127 10.1016/j.electacta.2021.138223 Spectroelectrochemistry Surface enhanced Raman scattering EC-SERS Electrochemical surface oxidation enhanced Raman scattering EC-SOERS Enhancement factors in electrochemical surface oxidation enhanced Raman scattering