2026-06-19T12:42:06Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/64262023-02-07T23:42:08Zcom_10259_3596com_10259_5086com_10259_2604col_10259_3597
Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process
Fernández-Fariña, Sandra
González-Barcia, Luis M.
Romero, María J.
García Tojal, Javier
Maneiro, Marcelino
Seco, José M.
Zaragoza, Guillermo
Martínez-Calvo, Miguel
González-Noya, Ana M.
Pedrido Castiñeiras, Rosa
We present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction.
2022-03-03
2022-03-03
2022-02
info:eu-repo/semantics/article
http://hdl.handle.net/10259/6426
10.1039/d1qi01308d
2052-1553
eng
Inorganic Chemistry Frontiers. 2022, V. 9, n. 3, p. 531-536
https://doi.org/10.1039/D1QI01308D
info:eu-repo/grantAgreement/Xunta de Galicia//ED431C 2017%2F01
info:eu-repo/grantAgreement/Xunta de Galicia//ED431C 2018%2F13
info:eu-repo/grantAgreement/Xunta de Galicia//ED431D 2017%2F01
info:eu-repo/grantAgreement/MICIU//CTQ2017-90802-REDT
info:eu-repo/grantAgreement/MICIU//RED2018-102471-T
info:eu-repo/semantics/openAccess
Royal Society of Chemistry