2026-06-19T13:20:07Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/64262023-02-07T23:42:08Zcom_10259_3596com_10259_5086com_10259_2604col_10259_3597

00925njm 22002777a 4500 dc Fernández-Fariña, Sandra author González-Barcia, Luis M. author Romero, María J. author García Tojal, Javier author Maneiro, Marcelino author Seco, José M. author Zaragoza, Guillermo author Martínez-Calvo, Miguel author González-Noya, Ana M. author Pedrido Castiñeiras, Rosa author 2022-02 We present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction. http://hdl.handle.net/10259/6426 10.1039/d1qi01308d 2052-1553 Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process