2026-06-21T14:02:17Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/64262023-02-07T23:42:08Zcom_10259_3596com_10259_5086com_10259_2604col_10259_3597

Fernández-Fariña, Sandra González-Barcia, Luis M. Romero, María J. García Tojal, Javier Maneiro, Marcelino Seco, José M. Zaragoza, Guillermo Martínez-Calvo, Miguel González-Noya, Ana M. Pedrido Castiñeiras, Rosa 2022-03-03T12:16:11Z 2022-03-03T12:16:11Z 2022-02 http://hdl.handle.net/10259/6426 10.1039/d1qi01308d 2052-1553 We present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction. eng info:eu-repo/semantics/openAccess Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process info:eu-repo/semantics/article