2026-06-19T12:58:38Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/73102023-01-25T08:28:48Zcom_10259_4201com_10259_5086com_10259_2604col_10259_4505
Repositorio Institucional de la Universidad de Burgos
author
Díaz Portugal, Andrés
author
Cuesta Segura, Isidoro Iván
author
Martínez Pañeda, Emilio
author
Alegre Calderón, Jesús Manuel
2023-01-24T12:51:56Z
2023-01-24T12:51:56Z
2020-05
0376-9429
http://hdl.handle.net/10259/7310
10.1007/s10704-019-00411-8
1573-2673
The electrochemical permeation test is one of the most used methods for characterising hydrogen diffusion in metals. The flux of hydrogen atoms registered in the oxidation cell might be fitted to obtain apparent diffusivities. The magnitude of this coefficient has a decisive influence on the kinetics of fracture or fatigue phenomena assisted by hydrogen and depends largely on hydrogen retention in microstructural traps. In order to improve the numerical fitting of diffusion coefficients, a permeation test has been reproduced using FEM simulations considering two approaches: a continuum 1D model in which the trap density, binding energy and the input lattice concentrations are critical variables and a polycrystalline model where trapping at grain boundaries is simulated explicitly including a segregation factor and a diffusion coefficient different from that of the interior of the grain. Results show that the continuum model captures trapping delay, but it should be modified to model the trapping influence on the steady state flux. Permeation behaviour might be classified according to different regimes depending on deviation from Fickian diffusion. Polycrystalline synthetic permeation shows a strong influence of segregation on output flux magnitude. This approach is able to simulate also the short-circuit diffusion phenomenon. The comparison between different grain sizes and grain boundary thicknesses by means of the fitted apparent diffusivity shows the relationships between the registered flux and the characteristic parameters of traps.
eng
Hydrogen diffusion
Permeation test
Finite element simulation
Grain boundary trapping
Analysis of hydrogen permeation tests considering two different modelling approaches for grain boundary trapping in iron
info:eu-repo/semantics/article
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URL
https://riubu.ubu.es/bitstream/10259/7310/1/Diaz-ijf_2020.pdf
File
MD5
a1bac9eb01c9e104405c278dab236cd5
1630708
application/pdf
Diaz-ijf_2020.pdf