2026-06-18T03:26:05Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/74122023-03-27T11:56:57Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

Solas Luera, Marta Suarez Pantiga, Samuel Sanz Díez, Roberto 2022 The asymmetric synthesis of cyclopentachromenones from gold-catalyzed reaction of readily available skipped alkenynones is described. This cascade reaction involves an initial anti-Michael hydroarylation of the ynone moiety to form a gold-functionalized dialkenylketone intermediate, followed by a Nazarov cyclization that proceeds in an unprecedented enantioselective manner. Excellent enantiomeric ratios and chemical yields are obtained under mild reaction conditions. application/pdf http://hdl.handle.net/10259/7412 eng Wiley Asymmetric Gold(I)‐Catalyzed Tandem Hydroarylation–Nazarov Cyclization: Enantioselective Access to Cyclopentenones info:eu-repo/semantics/article TEXT RIUBU. Repositorio Institucional de la Universidad de Burgos Hispana