2026-07-01T23:34:59Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/75382023-04-18T11:15:39Zcom_10259_4363com_10259_5086com_10259_2604com_10259_3596col_10259_4364col_10259_3597

00925njm 22002777a 4500 dc Jiménez Pérez, Alondra author Marcos-Gómez, Sara author Madariaga, Gotzon author Zapico, Manuel author Vitoria, Pablo author Tercero, Javier author Torres, M. Begoña author Lezama, Luis author Cuevas Vicario, José Vicente author Etxebarria, Íñigo author García Tojal, Javier author 2023-01 Experimental magnetic studies performed on the [{CuLX}2 ] system (HL = pyridine-2- carbaldehyde thiosemicarbazone, X = Cl−, Br−, I−) point to the larger electronegativity in X, the lower magnitude of the antiferromagnetic interactions. In order to confirm this and other trends observed and to dip into them, computational studies on the [{CuLX}2 ] (X = Cl− (1), I− (2)) compounds are here reported. The chemical and structural comparisons have been extended to the compounds obtained in acid medium. In this regard, chlorido ligands yield the [Cu(HL)Cl2 ]·H2O (3) complex, whose crystal structure shows that thiosemicarbazone links as a tridentate chelate ligand to square pyramidal Cu(II) ions. On the other hand, iodido ligands provoke the formation of the [{Cu(H2L)I2 }2 ] (4) derivative, which contains pyridine-protonated cationic H2L + as a S-donor monodentate ligand bonded to Cu(I) ions. Crystallographic, infrared and electron paramagnetic resonance spectroscopic results are discussed. Computational calculations predict a greater stability for the chlorido species, containing both the neutral (HL) and anionic (L−) ligand. The theoretical magnetic studies considering isolated dimeric entities reproduce the sign and magnitude of the antiferromagnetism in 1, but no good agreement is found for compound 2. The sensitivity to the basis set and the presence of interdimer magnetic interactions are debated. http://hdl.handle.net/10259/7538 10.3390/inorganics11010031 2304-6740 Chloro Coordination chemistry Copper Density functional theory Iodo Structure Thiosemicarbazone Thiosemicarbazonecopper/Halido Systems: Structure and DFT Analysis of the Magnetic Coupling