2026-05-04T08:07:11Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/76832025-06-10T07:22:52Zcom_10259_3844com_10259_5086com_10259_2604col_10259_7686col_10259_5684

00925njm 22002777a 4500 dc Olmo Alonso, Fabiola author Garoz Ruiz, Jesús author Heras Vidaurre, Aránzazu author Colina Santamaría, Álvaro author 2023-05-29 This work demonstrates how the way a chemical system is sampled plays a key role in spectroelectroanalysis, illustrated by the quantification of an analyte in presence of an antioxidant compound. For this purpose, bidimensional spectroelectrochemistry experiments were performed using epinephrine as the model analyte and ascorbic acid as antioxidant and interfering compound, as a proof of concept. This is the first time that three calibration curves are obtained simultaneously on a single spectroelectrochemistry data set, one for the electrochemical signal and two for the optical responses in normal and parallel configurations. The differences between the two optical arrangements, that are related to the diffusion process which is an essential feature for the spectroelectrochemical detection of compounds, have been experimentally demonstrated. As can be observed, the spectral signal in parallel configuration allows us to obtain the best analytical results, since in this configuration only the first micrometers of the solution adjacent to the electrode surface are sampled, thus removing the interfering effect of the antioxidant compound. This fact does not occur with either the electrochemical signal or the spectral response in normal configuration. Furthermore, it has been shown that the parallel configuration provides better results than the normal configuration in terms of sensitivity. In summary, epinephrine is successfully detected in a simple and effective way, even in the presence of a direct antioxidant compound such as ascorbic acid at different concentrations levels, which makes spectroelectrochemistry a good choice for quantitative analysis. Olmo Alonso, Fabiola; Garoz Ruiz, Jesús; Heras Vidaurre, Aránzazu; Colina Santamaría, Álvaro; 2023; Dataset of the work “Normal or parallel configuration in spectroelectrochemistry? Bidimensional spectroelectroanalysis in presence of an antioxidant compound”; RIUBU; http://doi.org/10.71486/w30e-7g37 http://hdl.handle.net/10259/7683 10.71486/w30e-7g37 Bidimensional Spectroelectrochemistry Adrenaline Ascorbic acid Quantitative Analysis Dataset of the work “Normal or parallel configuration in spectroelectrochemistry? Bidimensional spectroelectroanalysis in presence of an antioxidant compound”