2026-06-17T18:29:21Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/77122024-04-12T11:34:15Zcom_10259_4201com_10259_5086com_10259_2604col_10259_4505

Peral, Luis Borja Díaz Portugal, Andrés Alegre Calderón, Jesús Manuel Cuesta Segura, Isidoro Iván 2023-06-20T12:41:23Z 2023-06-20T12:41:23Z 2023-06 0360-3199 http://hdl.handle.net/10259/7712 10.1016/j.ijhydene.2023.05.286 To better understand hydrogen uptake kinetics, electrochemical permeation tests have been performed in a quenched and tempered low-alloy steel. Hydrogen uptake and transport has been studied with three different surface roughness, in four different solutions (1 M H2SO4, 1 M H2SO4+As2O3, 0.1 M NaOH and 3.5% NaCl) and two different hydrogen charging current densities (1 and 5 mA/cm2). A strong effect of the charging solution, current density and surface roughness has been demonstrated. In 1 M H2SO4 + As2O3 solution and 5 mA/cm2, hydrogen recombination on the surface of the samples is strongly reduced and interstitial diffusion prevails due to the trap saturation ( ). However, in 1 M H2SO4, 0.1 M NaOH and 3.5% NaCl, hydrogen transport is dominated by trapping and detrapping processes ( ). Permeation transients are numerically reproduced through Finite Element simulations and compared to the experimental results. The relationship between hydrogen diffusion kinetics at the microstructural level and surface effects is clearly established by a mapping strategy obtained from the wide range of experimental results, combined with a numerical approach. The authors would like to thank the Spanish Government for the financial support received to perform the research projects RTI2018-096070-B-C33 and PID2021-124768OB-C21. This work was supported by the Regional Government of Castilla y León (Junta de Castilla y León) and by the Ministry of Science and Innovation MICIN and the European Union Next Generation EU/PRTR (MR4W.P2 and MR5W.P3). L.B. Peral is also grateful for his Margarita Salas Postdoctoral contract (Ref.: MU-21-UP2021-030) funded by the University of Oviedo through the Next Generation European Union. application/pdf eng Elsevier International Journal of Hydrogen Energy. 2023 https://doi.org/10.1016/j.ijhydene.2023.05.286 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-096070-B-C33/ES/DESARROLLO Y VALIDACION DE MODELOS DE FRAGILIZACION ASISTIDA POR HIDROGENO PARA SU APLICACION AL DISEÑO DE RECIPIENTES SOLDADOS Y SOMETIDOS A ALTAS PRESIONES/ info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica, Técnica y de Innovación 2021-2023/PID2021-124768OB-C21/ES/Modelado de efectos y aplicaciones del hidrógeno en aceros de fabricación aditiva/ info:eu-repo/grantAgreement/Junta de Castilla y León//MR4WP2//Plan Complementario de Materiales Avanzados: subproyecto GIE/ info:eu-repo/grantAgreement/Junta de Castilla y León//MR5WP3//Planes complementarios de I+D+i, Tecnologías, materiales y procesos para producción a pequeña escala de portadores de Hidrógeno Renovable (Metano y Amoniaco) para aprovechamiento distribuido en CyL. Universidad de Burgos. Grupo GIE/ info:eu-repo/grantAgreement/Universidad de Oviedo//MU-21-UP2021-030/ Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess CrMo steel Surface science Electrochemistry at surfaces Hydrogen permeation Hydrogen trapping and diffusion Numerical modelling Ingeniería civil Resistencia de materiales Civil engineering Strength of materials Hydrogen uptake and diffusion kinetics in a quenched and tempered low carbon steel: experimental and numerical study info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion International Journal of Hydrogen Energy