2026-06-17T21:13:57Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/77122024-04-12T11:34:15Zcom_10259_4201com_10259_5086com_10259_2604col_10259_4505

00925njm 22002777a 4500 dc Peral, Luis Borja author Díaz Portugal, Andrés author Alegre Calderón, Jesús Manuel author Cuesta Segura, Isidoro Iván author 2023-06 To better understand hydrogen uptake kinetics, electrochemical permeation tests have been performed in a quenched and tempered low-alloy steel. Hydrogen uptake and transport has been studied with three different surface roughness, in four different solutions (1 M H2SO4, 1 M H2SO4+As2O3, 0.1 M NaOH and 3.5% NaCl) and two different hydrogen charging current densities (1 and 5 mA/cm2). A strong effect of the charging solution, current density and surface roughness has been demonstrated. In 1 M H2SO4 + As2O3 solution and 5 mA/cm2, hydrogen recombination on the surface of the samples is strongly reduced and interstitial diffusion prevails due to the trap saturation ( ). However, in 1 M H2SO4, 0.1 M NaOH and 3.5% NaCl, hydrogen transport is dominated by trapping and detrapping processes ( ). Permeation transients are numerically reproduced through Finite Element simulations and compared to the experimental results. The relationship between hydrogen diffusion kinetics at the microstructural level and surface effects is clearly established by a mapping strategy obtained from the wide range of experimental results, combined with a numerical approach. 0360-3199 http://hdl.handle.net/10259/7712 10.1016/j.ijhydene.2023.05.286 CrMo steel Surface science Electrochemistry at surfaces Hydrogen permeation Hydrogen trapping and diffusion Numerical modelling Hydrogen uptake and diffusion kinetics in a quenched and tempered low carbon steel: experimental and numerical study