2026-05-29T21:00:18Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/77122024-04-12T11:34:15Zcom_10259_4201com_10259_5086com_10259_2604col_10259_4505
Repositorio Institucional de la Universidad de Burgos
author
Peral, Luis Borja
author
Díaz Portugal, Andrés
author
Alegre Calderón, Jesús Manuel
author
Cuesta Segura, Isidoro Iván
2023-06-20T12:41:23Z
2023-06-20T12:41:23Z
2023-06
0360-3199
http://hdl.handle.net/10259/7712
10.1016/j.ijhydene.2023.05.286
To better understand hydrogen uptake kinetics, electrochemical permeation tests have been performed in a quenched and tempered low-alloy steel. Hydrogen uptake and transport has been studied with three different surface roughness, in four different solutions (1 M H2SO4, 1 M H2SO4+As2O3, 0.1 M NaOH and 3.5% NaCl) and two different hydrogen charging current densities (1 and 5 mA/cm2). A strong effect of the charging solution, current density and surface roughness has been demonstrated. In 1 M H2SO4 + As2O3 solution and 5 mA/cm2, hydrogen recombination on the surface of the samples is strongly reduced and interstitial diffusion prevails due to the trap saturation (
). However, in 1 M H2SO4, 0.1 M NaOH and 3.5% NaCl, hydrogen transport is dominated by trapping and detrapping processes (
). Permeation transients are numerically reproduced through Finite Element simulations and compared to the experimental results. The relationship between hydrogen diffusion kinetics at the microstructural level and surface effects is clearly established by a mapping strategy obtained from the wide range of experimental results, combined with a numerical approach.
eng
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
CrMo steel
Surface science
Electrochemistry at surfaces
Hydrogen permeation
Hydrogen trapping and diffusion
Numerical modelling
Hydrogen uptake and diffusion kinetics in a quenched and tempered low carbon steel: experimental and numerical study
info:eu-repo/semantics/article
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URL
https://riubu.ubu.es/bitstream/10259/7712/1/Peral-ijhe_2023.1.pdf
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Peral-ijhe_2023.1.pdf