2026-04-21T10:41:14Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/78572023-10-11T00:05:33Zcom_10259_5498com_10259_5086com_10259_2604com_10259_4313col_10259_5499col_10259_4314

2023-10-10T11:42:06Z urn:hdl:10259/7857 Metal-free organocatalysts for high hydrolytic stability single component polyurethane adhesives and their application in decorative insulation facades manufacturing Vallejos Calzada, Saúl Trigo López, Miriam Sardon, Haritz González Martín, José Manuel González Moreno, Sara García Pérez, José Miguel Siliciclastic sandstone Single-component polyurethane adhesive Metal-free catalyst Colorimetry RGB parameters Homemade stability measurement system DBU Naphthoic acid Fan Facades We focused on developing polyurethane (PU) adhesives with superior ambient thermal and hydrolytic stability, a crucial factor for industrial productivity. Our approach involved creating PU prepolymers that can withstand varying temperatures in ambient conditions. These prepolymers consist of conventional isocyanate-terminated polyurethane and metal-free acid:base organic catalysts, with the stability of the adhesive relying on the organocatalyst employed. We tested a series of 11 latent organocatalysts derived from the reaction between 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and various acids. Among these, the catalyst based on 1-naphthoic acid exhibited exceptional stability, lasting at least 3 h at 60 ◦C and an average relative humidity of 65% under vigorous stirring. We assessed this stability using a fan-based stirrer and analyzed the curing conditions kinetically through DSC. Furthermore, our adhesive formulation is environmentally friendly as it is free of metals, specifically tin (typically present in catalysts such as dibutyltin dilaurate). This quality enhances its sustainability. To validate the practical applicability of the adhesives, we conducted tests using decorative facade models composed of siliciclastic sandstone extracted from a quarry in Vilviestre del Pinar (Burgos, Spain. Latitude: 41.951024◦N, longitude: 3.078283◦W) and extruded polystyrene (XPS). The results demonstrated the excellent hydrolytic and thermal stability of the adhesives, highlighting their significant potential for panel manufacturing in this context. 2023-10-10T11:42:06Z 2023-10-10T11:42:06Z 2023-10 info:eu-repo/semantics/article 0950-0618 http://hdl.handle.net/10259/7857 10.1016/j.conbuildmat.2023.132643 eng Construction and Building Materials. 2023, V. 400, 132643 https://doi.org/10.1016/j.conbuildmat.2023.132643 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113264RB-I00/ES/DISEÑO, SINTESIS Y CARACTERIZACION DE POLIMEROS INTELIGENTES. APLICACION DE SENSORES QUIMICOS POLIMERICOS EN CONTROL Y SEGURIDAD ALIMENTARIA Y EN EL AMBITO SANITARIO/ info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-108583RJ-I00/ES/POLIAMIDAS AROMATICAS MICRO Y NANOCELULARES REFORZADAS COMO MATERIALES DE ALTAS PRESTACIONES EN APLICACIONES DE SEGURIDAD, PROTECCION Y TRANSPORTE/ info:eu-repo/grantAgreement/MIU/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/BG22%2F00086/ES/ http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess Atribución 4.0 Internacional Elsevier