2026-04-21T12:07:21Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/93242024-07-02T00:05:29Zcom_10259_3596com_10259_5086com_10259_2604com_10259_3593col_10259_3597col_10259_3594
Gómez Gil, Sara
c17cf50a-843a-443e-92b1-6a5607b46351
600
Rubio Presa, Rubén
493
600
0000-0002-9938-2058
Hernández Ruiz, Raquel
277
600
0000-0001-5018-0845
Suarez Pantiga, Samuel
544
600
0000-0002-4249-7807
Pedrosa Sáez, María de los Remedios
422
600
0000-0001-7083-8093
Sanz Díez, Roberto
531
600
0000-0003-2830-0892
2024-07-01T06:55:22Z
2024-07-01T06:55:22Z
2023-04-26
1477-0520
http://hdl.handle.net/10259/9324
10.1039/D3OB00436H
1477-0539
A new two-step procedure for the synthesis of 1,4-dicarbonyls has
been developed involving an efficient and clean Mo-catalyzed oxidative cleavage of cyclobutane-1,2-diols with DMSO, which is used
as solvent and oxidant. The required starting glycols were prepared
by nucleophilic additions of organolithiums and Grignard reagents
to easily available 2-hydroxycyclobutanones.
We gratefully acknowledge Ministerio de Ciencia e Innovación and FEDER (PID2020-115789GB-C21), and Junta de Castilla y León and FEDER (BU049P20) for financial support. S. G.-G. and R. H.-R. thank Ministerio de Educación for FPU predoctoral contracts. S. S.-P. thanks Ministerio de Ciencia e Innovación and “NextGenerationEU”/PRTR EU for a Ramón y Cajal contract (RYC2021-031533-I).
application/pdf
eng
Royal Society of Chemistry
Organic & Biomolecular Chemistry. 2023, V. 21, n. 20, p. 4185-4190
https://doi.org/10.1039/D3OB00436H
Atribución-NoComercial 4.0 Internacional
http://creativecommons.org/licenses/by-nc/4.0/
info:eu-repo/semantics/openAccess
Química orgánica
Biología molecular
Chemistry, Organic
Molecular biology
Synthesis of 1,4-ketoaldehydes and 1,4-diketones by Mo-catalyzed oxidative cleavage of cyclobutane-1,2-diols
info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Organic & Biomolecular Chemistry
21
20
4185
4190
THUMBNAIL
Gomez-obc_2023.pdf.jpg
Gomez-obc_2023.pdf.jpg
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4189
https://riubu.ubu.es/bitstream/10259/9324/4/Gomez-obc_2023.pdf.jpg
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LICENSE
license.txt
license.txt
text/plain; charset=utf-8
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https://riubu.ubu.es/bitstream/10259/9324/3/license.txt
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CC-LICENSE
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https://riubu.ubu.es/bitstream/10259/9324/2/license_rdf
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ORIGINAL
Gomez-obc_2023.pdf
Gomez-obc_2023.pdf
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https://riubu.ubu.es/bitstream/10259/9324/1/Gomez-obc_2023.pdf
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10259/9324
oai:riubu.ubu.es:10259/9324
2024-07-02 02:05:29.65
Repositorio Institucional de la Universidad de Burgos
bubrep@ubu.es
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