2024-03-28T18:49:01Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/51372022-12-19T10:46:19Zcom_10259_3924com_10259_5086com_10259_2604col_10259_3925
2019-08-20T09:04:19Z
urn:hdl:10259/5137
Bis(imidazolium) salts derived from amino acids as receptors and transport agents for chloride anions
González Mendoza, Laura
Altava, Belén
Burguete, M. Isabel
Escorihuela, Jorge
Hernando Santa Cruz, Elsa
Luis, Santiago V.
Quesada Pato, Roberto
Vicent, Cristian
The binding properties of bis(imidazolium) hosts 1a–c derived from amino acids towards different anions have been studied by 1H NMR titration experiments in 95 : 05 CD3CN : H2O at 303 K, ESI-MS and theoretical calculations. Among this family, the salt 1c showed a strong and high selectivity for chloride anions. Transmembrane chloride transport activity has also been studied for the three bis(imidazolium) based transporters in POPC liposome models, and compound 1a was identified as an active chloride/nitrate exchanger.
2019-08-20T09:04:19Z
2019-08-20T09:04:19Z
2015-04
info:eu-repo/semantics/article
2046-2069
http://hdl.handle.net/10259/5137
10.1039/C5RA05880E
eng
RSC Advances. 2015. V. 5, n. 43, p. 34415-34423
https://doi.org/10.1039/C5RA05880E
info:eu-repo/grantAgreement/MINECO/CTQ2011-28903-C02-01
info:eu-repo/grantAgreement/GVA/PROMETEO 2012/020)
info:eu-repo/grantAgreement/UJI/P11B2013-38
info:eu-repo/grantAgreement/JCyL/BU340U13
info:eu-repo/grantAgreement/Fundació la Marató de TV3/20132730
http://creativecommons.org/licenses/by-nc/4.0/
info:eu-repo/semantics/openAccess
Attribution-NonCommercial 4.0 International
Royal Society of Chemistry