2024-03-28T22:48:29Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/39082021-11-10T09:38:24Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
García García, Patricia
Martínez Cuezva, Alberto
Sanjuán Cortázar, Ana María
Fernández Rodríguez, Manuel A.
Sanz Díez, Roberto
2016-01-20T12:31:52Z
2016-01-20T12:31:52Z
2011-08
1523-7060
http://hdl.handle.net/10259/3908
10.1021/ol202129n
Highly substituted benzene derivatives have been easily prepared in a regioselective way from readily available 1,3-hexadien-5-ynes through a gold(I)-catalyzed tandem reaction. The process involves an initial cyclization followed by a selective Wagner-Meerwein shift in which the migration preference seems to be determined by the ability to stabilize a positive charge
Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial suport. A.M. S. thanks Junta de Castilla y Leon for a predoctoral fellowship. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts
Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial suport. A.M. S. thanks Junta de Castilla y Leon for a predoctoral fellowship. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic letters, copyright © American Chemical Society after peer review and technical editing by the publisher.
application/pdf
eng
American Chemical Society
Organic Letters. 2011, V. 13, n. 18, p. 4970-4973
http://dx.doi.org/10.1021/ol202129n
info:eu-repo/grantAgreement/MICINN/CTQ2010-15358
info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU
info:eu-repo/grantAgreement/JCyL/BU021A09
info:eu-repo/grantAgreement/JCyL/GR-172
Química orgánica
Chemistry, Organic
Gold(I)-Catalyzed Tandem Cyclization–Selective Migration Reaction of 1,3-Dien-5-ynes: Regioselective Synthesis of Highly Substituted Benzenes
info:eu-repo/semantics/acceptedVersion
info:eu-repo/semantics/article
info:eu-repo/semantics/openAccess