2024-03-29T15:08:03Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/42892021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597
A Selective, Efficient and Environmentally Friendly Method for the Oxidative Cleavage of Glycols
García Bartolomé, Nuria
Rubio Presa, Rubén
García García, Patricia
Fernández Rodríguez, Manuel A.
Pedrosa Sáez, María de los Remedios
Arnáiz García, Francisco Javier
Sanz Díez, Roberto
Química orgánica
Chemistry, Organic
A catalytic methodology for the oxidative cleavage of vicinal diols is described as an advantageous alternative in terms of the environmental impact on classical methods involving toxic oxidants. The novel strategy is based on the use of dioxomolybdenum(VI) complexes as catalysts and dimethyl sulfoxide (DMSO) as an oxidant and displays high selectivity and a broad scope for glycol cleavage. In addition, the developed system is also useful for the oxidation of acyloins to diketones.
Ministerio de Economía y Competitividad
(MINECO) and FEDER (CTQ2013-48937-C2-1-P) and Junta
de Castilla y León (BU237U13)
2016-12-01T11:24:42Z
2017-04-21T02:45:06Z
2016-04
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
1463-9262
http://hdl.handle.net/10259/4289
10.1039/c5gc02862k
eng
Green Chemistry. 2016, V. 18, n. 8, p. 2335-2340
http://dx.doi.org/10.1039/c5gc02862k
info:eu-repo/grantAgreement/MINECO-FEDER/CTQ2013-48937-C2-1-P
info:eu-repo/grantAgreement/JCyL/BU237U13
info:eu-repo/semantics/openAccess
application/pdf
Royal Society of Chemistry
https://riubu.ubu.es/bitstream/10259/4289/4/Garc%c3%ada-GC_2016.pdf.jpg
Hispana
TEXT
http://rightsstatements.org/vocab/CNE/1.0/
RIUBU. Repositorio Institucional de la Universidad de Burgos
http://hdl.handle.net/10259/4289