2024-03-29T13:06:02Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/49502022-12-19T10:50:36Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845
Silver nanoparticles/free-standing carbon nanotube Janus membranes
Ibáñez Martínez, David
Galindo, M.
Colina Santamaría, Álvaro
Valles, Elisa
Heras Vidaurre, Aránzazu
Gómez, Elvira
Janus materials
free-standing electrodes
silver nanoparticles
ionic liquids
spectroelectrochemistry
Química analítica
Chemistry, Analytic
Janus materials are attracting intense interest due to their exceptional possibilities in the design of structures with specific properties. In this work, Janus structures were constructed by the functionalization of free-standing single-walled carbon nanotube (FS-SWCNT) membranes with silver nanoparticles (AgNPs) electrodeposited on one face of the free-standing structure. The modification of the FS-SWCNT films with AgNPs was carried out from an ionic liquid solution, a green and environmentally friendly procedure. Before the functionalization of the free-standing membranes, the optimal electrodeposition conditions of AgNPs from an ionic liquid in different carbon substrates were studied. We demonstrate by UV–vis spectroelectrochemistry that the functionalization of the FS-SWCNT membranes on only one face is achieved, remaining unmodified the other face, as SEM images confirm. Moreover, the morphology of AgNPs, and, consequently, the properties of the Janus structures strongly depend on the specific electrodeposition conditions selected, determining their future applicability.
Ministerio de Economía y Competitividad (CTQ2014-61914-EXP, CTQ2014-55583-R, TEC2014-51940-C2-2R, CTQ2015-71955-REDT) and Junta de Castilla y León (BU033-U16)
Ministerio de Economía y Competitividad (CTQ2014-61914-EXP, CTQ2014-55583-R, TEC2014-51940-C2-2R, CTQ2015-71955-REDT) and Junta de Castilla y León (BU033-U16)
2018-09-13T07:21:59Z
2017-07
2020-08
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
0013-4686
http://hdl.handle.net/10259/4950
10.1016/j.electacta.2017.04.106
eng
Electrochimica Acta. 2017, V. 243, p. 349-356
https://doi.org/10.1016/j.electacta.2017.04.106
info:eu-repo/grantAgreement/MINECO/CTQ2014-61914-EXP
info:eu-repo/grantAgreement/MINECO/CTQ2014-55583-R
info:eu-repo/grantAgreement/MINECO/TEC2014-51940-C2-2R
info:eu-repo/grantAgreement/MINECO/CTQ2015-71955-REDT
info:eu-repo/grantAgreement/JCyL/BU033-U16
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
application/pdf
Elsevier
https://riubu.ubu.es/bitstream/10259/4950/8/Ib%c3%a1%c3%b1ez-ea_2017.pdf.jpg
Hispana
TEXT
http://creativecommons.org/licenses/by-nc-nd/4.0/
RIUBU. Repositorio Institucional de la Universidad de Burgos
http://hdl.handle.net/10259/4950