2024-03-28T09:18:42Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/49202021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
00925njm 22002777a 4500
dc
Virumbrales, Cintia
author
Suarez Pantiga, Samuel
author
Solas Luera, Marta
author
Fernández Rodríguez, Manuel A.
author
Sanz Díez, Roberto
author
2018-04
The gold(I)-catalyzed oxycyclization of β-aryl monosubstituted
o-(alkynyl)styrenes gives rise to 1-α-methoxy or 1-α-hydroxybenzyl-
1H-indenes in a diastereospecific way. In contrast to
β,β-disubstituted o-(alkynyl)styrenes, the stereochemical outcome
of this process, diastereospecific reaction supports the higher contribution
of a gold intermediate with a cyclopropylcarbene-like
character.
1477-0520
http://hdl.handle.net/10259/4920
10.1039/c8ob00406d
Gold(I)-catalyzed diastereoselective synthesis of 1-α-oxybenzyl-1H-indenes