2024-03-28T22:01:08Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/64262023-02-07T23:42:08Zcom_10259_3596com_10259_5086com_10259_2604col_10259_3597
Fernández-Fariña, Sandra
González-Barcia, Luis M.
Romero, María J.
García Tojal, Javier
Maneiro, Marcelino
Seco, José M.
Zaragoza, Guillermo
Martínez-Calvo, Miguel
González-Noya, Ana M.
Pedrido Castiñeiras, Rosa
2022-03-03T12:16:11Z
2022-03-03T12:16:11Z
2022-02
http://hdl.handle.net/10259/6426
10.1039/d1qi01308d
2052-1553
We present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction.
eng
info:eu-repo/semantics/openAccess
Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process
info:eu-repo/semantics/article