2024-03-29T10:55:43Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/38022022-12-20T11:04:13Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597
An unprecedented use for glycerol: chemoselective reducing agent for sulfoxides
García Bartolomé, Nuria
García García, Patricia
Fernández Rodríguez, Manuel A.
García, Daniel
Pedrosa Sáez, María de los Remedios
Arnáiz García, Francisco Javier
Sanz Díez, Roberto
Química orgánica
Chemistry, Organic
A new application for glycerol that expands its possibilities beyond a green solvent and a precursor of
value-added products has been demonstrated. Simple, easily available, and environmentally friendly dioxomolybdenum(
VI) complexes are highly efficient catalysts for the chemoselective sulfoxide deoxygenation
with this biomass-derived chemical feedstock. Both refined glycerol and crude glycerin can be used, thus
expanding the potential application of this reaction. Subsequent transformation of glycerol during this
reductive process has also been investigated
Ministerio de Ciencia e Innovacion (MICINN), FEDER (CTQ2010-15358 and CTQ2009-09949/BQU), Junta de Castilla y Leon (BU021A09 and GR-172), MICINN ("Juan de la Cierva" and "Ramon y Cajal" contracts for P.G.-G. and M.A.F.-R.)
2015-07-28T09:55:41Z
2015-07-28T09:55:41Z
2013-02
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
http://hdl.handle.net/10259/3802
10.1039/c3gc36908k
eng
Green Chemistry. 2013, V. 15, n. 4, p. 999-1005
http://pubs.rsc.org/en/journals/journalissues/gc#!recentarticles&adv
info:eu-repo/grantAgreement/FEDER/CTQ2010-15358
info:eu-repo/grantAgreement/FEDER/CTQ2009-09949/BQU
info:eu-repo/grantAgreement/JCyL/BU021A09
info:eu-repo/grantAgreement/JCyL/GR-172
info:eu-repo/semantics/openAccess
application/pdf
Royal Society of Chemistry