2024-03-28T11:20:58Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/42742022-12-19T11:11:11Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
1,3-Dien-5-ynes: Versatile Building Blocks for the Synthesis of Carbo- and Heterocycles
Aguilar, Enrique
Sanz Díez, Roberto
Fernández Rodríguez, Manuel A.
García García, Patricia
Chemistry, Organic
Química orgánica
1,3-Dien-5-ynes have been extensively used as starting materials for the
synthesis of a wide number of different carbo- and heterocycles. The aim of this review is
to give an overview of their utility in organic synthesis, highlighting the variety of
compounds that can be directly accessed from single reactions over these systems. Thus,
cycloaromatization processes are initially commented, followed by reactions directed
toward the syntheses of five-membered rings, other carbocycles and, finally, heterocycles.
The diverse methodologies that have been developed for the synthesis of each of these
types of compounds from 1,3-dien-5-ynes are presented, emphasizing the influence of
the reaction conditions and the use of additional reagents in the outcome of the
transformations.
Ministerio de Economía
y Competitividad
(MINECO) and FEDER (CTQ2013-41336-P, CTQ2013-
48937-C2-1-P, and CTQ2014-52488-R), Universidad de Alcalá
(CCG2015/EXP-003) and Junta de Castilla y León
(BU237U13)
2016-11-21T08:17:39Z
2017-07-27T02:45:06Z
2016-07
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
0009-2665
http://hdl.handle.net/10259/4274
eng
Chemical Reviews, 2010, V. 116, n. 14, p. 8256–8311
http://dx.doi.org/10.1021/acs.chemrev.6b00181
info:eu-repo/semantics/openAccess
application/pdf
American Chemical Society