2024-03-29T06:44:06Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/38932022-12-20T11:48:42Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes
Sanjuán Cortázar, Ana María
García García, Patricia
Fernández Rodríguez, Manuel A.
Sanz Díez, Roberto
cycloisomerization
cyclopentadienes
Diels–Alder reaction
dienynes
gold
An asymmetric synthesis of elusive chiral cyclopentadienes has been developed by gold(I)-catalyzed alkoxycyclization of 1,3-dien-5-ynes. The application of these substrates in completely diastereoselective Diels–Alder cycloaddition reactions, which can be carried out in one pot from achiral 1,3-dien-5-ynes, allows the preparation of highly functionalized products bearing five stereogenic centers with high enantiomeric excesses
2015-12-10T10:56:51Z
2015-12-10T10:56:51Z
2015-12-10T10:56:51Z
2013-07
info:eu-repo/semantics/article
1615-4150
http://hdl.handle.net/10259/3893
10.1002/adsc.201300448
eng
Advanced Synthesis & Catalysis. 2013, V. 355, n. 10, p. 1955–1962
http://dx.doi.org/10.1002/adsc.201300448
info:eu-repo/grantAgreement/MICINN/CTQ2010-15358
info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU
info:eu-repo/grantAgreement/JCyL/BU021A09
info:eu-repo/grantAgreement/JCyL/GR-172
info:eu-repo/semantics/openAccess
Wiley-VCH Verlag