2024-03-29T06:26:35Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/38902022-04-29T11:09:58Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597
Pinacol as a new green reducing agent: molybdenum-catalyzed chemoselective reduction of sulfoxides and nitroaromatics
García Bartolomé, Nuria
García García, Patricia
Fernández Rodríguez, Manuel A.
Rubio Presa, Rubén
Pedrosa Sáez, María de los Remedios
Arnáiz García, Francisco Javier
Sanz Díez, Roberto
chemoselectivity
molybdenum
nitro compounds
reduction
sulfoxides
Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions
2015-12-01T12:35:17Z
2015-12-01T12:35:17Z
2012-02
info:eu-repo/semantics/article
1615-4150
http://hdl.handle.net/10259/3890
10.1002/adsc.201100877
eng
Advanced Synthesis & Catalysis. 2012, V. 354, n. 2-3, p. 321–327
http://dx.doi.org/10.1002/adsc.201100877
info:eu-repo/grantAgreement/MICINN/CTQ2010-15358
info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU
info:eu-repo/grantAgreement/JCyL/BU021 A09
info:eu-repo/grantAgreement/JCyL/GR-172
info:eu-repo/semantics/openAccess
Wiley-VCH Verlag