2024-03-28T09:24:26Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/61792022-11-24T11:40:05Zcom_10259_4323com_10259_5086com_10259_2604col_10259_4330
A combined experimental and theoretical study on diglyme + 1-alkanol liquid mixtures
Trenzado, J.L. .
Rozas Azcona, Sara
Caro, M.N.
Atilhan, Mert .
Aparicio Martínez, Santiago
Liquid mixtures
Glymes
Alcohols
Hydrogen bonding
Thermophysics
Molecular simulation
The properties, structuring and intermolecular forces of diglyme + alkanol mixtures are studied using a
combined experimental and theoretical approach. The thermophysical properties as well as the molecular
simulation results provide detailed characterization of the mixtures in terms of composition, type of
1-alkanol and temperature. The possibility of development of heteroassociations by glyme - alkanol
hydrogen bonding as well as their effect on the weakening and breaking on alkanols self-association
show a pivotal role on the mixtures structure as well as the glyme self-association. The reported mixtures
show complex structural effects varying with mixtures composition which may be considered as model
of ether – hydroxyl interaction and their effects on the mixture’s properties and nature.
2021-11-18T13:27:01Z
2021-11-18T13:27:01Z
2021-07
info:eu-repo/semantics/article
0167-7322
http://hdl.handle.net/10259/6179
10.1016/j.molliq.2021.116048
eng
Journal of Molecular Liquids. 2021, V. 334, 116048
https://doi.org/10.1016/j.molliq.2021.116048
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101987-B-I00/ES/NANOCOMPOSITES POROSOS DE LIQUIDOS IONICOS PARA EL ALMACENAMIENTO DE METANO
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Elsevier