2024-03-28T17:02:14Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/38932022-12-20T11:48:42Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
Sanjuán Cortázar, Ana María
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600
García García, Patricia
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Fernández Rodríguez, Manuel A.
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Sanz Díez, Roberto
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0000-0003-2830-0892
2015-12-10T10:56:51Z
2015-12-10T10:56:51Z
2013-07
1615-4150
http://hdl.handle.net/10259/3893
10.1002/adsc.201300448
An asymmetric synthesis of elusive chiral cyclopentadienes has been developed by gold(I)-catalyzed alkoxycyclization of 1,3-dien-5-ynes. The application of these substrates in completely diastereoselective Diels–Alder cycloaddition reactions, which can be carried out in one pot from achiral 1,3-dien-5-ynes, allows the preparation of highly functionalized products bearing five stereogenic centers with high enantiomeric excesses
Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial support. A. M. S. thanks Junta de Castilla y Leon (Consejeria de Educacion) and Fondo Social Europeo for a PIRTU contract. P. G.-G. and M. A. F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts
This is the peer reviewed version of the following article: Sanjuán, A. M., García-García, P., Fernández-Rodríguez, M. A. and Sanz, R. (2013), Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes. Adv. Synth. Catal., 355: 1955–1962. doi: 10.1002/adsc.201300448, which has been published in final form at 10.1002/adsc.201300448. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
application/pdf
eng
Wiley-VCH Verlag
Advanced Synthesis & Catalysis. 2013, V. 355, n. 10, p. 1955–1962
http://dx.doi.org/10.1002/adsc.201300448
info:eu-repo/grantAgreement/MICINN/CTQ2010-15358
info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU
info:eu-repo/grantAgreement/JCyL/BU021A09
info:eu-repo/grantAgreement/JCyL/GR-172
cycloisomerization
cyclopentadienes
Diels–Alder reaction
dienynes
gold
Química orgánica
Chemistry, Organic
Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
info:eu-repo/semantics/openAccess
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oai:riubu.ubu.es:10259/3893
2022-12-20 12:48:42.936
Repositorio Institucional de la Universidad de Burgos
bubrep@ubu.es
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