RT info:eu-repo/semantics/article T1 Ultrafast Metal‐Free Microsupercapacitor Arrays Directly Store Instantaneous High‐Voltage Electricity from Mechanical Energy Harvesters A1 Chen, Shiqian A1 Li, Zheng A1 Huang, Po‐Han A1 Ruiz Fernández, Virginia A1 Su, Yingchun A1 Fu, Yujie A1 Alesanco, Yolanda A1 Malm, B. Gunnar A1 Niklaus, Frank A1 Li, Jiantong K1 Droplet-based electrcity generators K1 Full printing K1 Microsupercapacitor arrays K1 On-paper electronics K1 PEDOT:PSS K1 Química analítica K1 Chemistry, Analytic K1 Electroquímica K1 Electrochemistry AB Harvesting renewable mechanical energy is envisioned as a promising and sustainable way for power generation. Many recent mechanical energy harvesters are able to produce instantaneous (pulsed) electricity with a high peak voltage of over 100 V. However, directly storing such irregular high-voltage pulse electricity remains a great challenge. The use of extra power management components can boost storage efficiency but increase system complexity. Here utilizing the conducting polymer PEDOT:PSS, high-rate metal-free micro-supercapacitor (MSC) arrays are successfully fabricated for direct high-efficiency storage of high-voltage pulse electricity. Within an area of 2.4 × 3.4 cm2 on various paper substrates, large-scale MSC arrays (comprising up to 100 cells) can be printed to deliver a working voltage window of 160 V at an ultrahigh scan rate up to 30 V s−1. The ultrahigh rate capability enables the MSC arrays to quickly capture and efficiently store the high-voltage (≈150 V) pulse electricity produced by a droplet-based electricity generator at a high efficiency of 62%, significantly higher than that (<2%) of the batteries or capacitors demonstrated in the literature. Moreover, the compact and metal-free features make these MSC arrays excellent candidates for sustainable high-performance energy storage in self-charging power systems. PB Wiley SN 2198-3844 YR 2024 FD 2024-03 LK http://hdl.handle.net/10259/10299 UL http://hdl.handle.net/10259/10299 LA eng NO The authors acknowledge the financial support from the Swedish ResearchCouncil (Grant No. 2019–04731), the European Commission (Grant No.101070255, REFORM), and the Swedish Foundation for International Co-operation in Research and Higher Education (STINT, CH2017-7284). DS Repositorio Institucional de la Universidad de Burgos RD 14-mar-2025