RT info:eu-repo/semantics/article
T1 Tailoring Deep Eutectic Solvents: The Role of Hydrated Metal Salts in Modifying Structural Organization and Macroscopic Performance
A1 Pérez Durán, Guadalupe
A1 Hossain, Hamza I.
A1 Muñoz Quintana, Enrique
A1 Castillo Felix, Luis Antonio
A1 Paul, Supti
A1 Aparicio Martínez, Santiago
A1 Gutiérrez Vega, Alberto
A1 Iglesias Silva, Gustavo A.
A1 Atilhan, Mert
K1 Thermodynamic properties
K1 Anions
K1 Solvents
K1 Salts
K1 Metals
K1 Disolventes
K1 Solvents
K1 Sales
K1 Salts
AB Deep eutectic solvents (DES) have emerged as promising green alternatives to conventional solvents; however, their broader implementation remains limited by the scarcity of reliable thermophysical and interfacial property data, particularly for multicomponent systems. In this work, a systematic experimental characterization was carried out on a ternary DES based on ChCl:Gly (1:2) incorporating hydrated metal salts. Systems containing AlCl3·6H2O, MgCl2·6H2O, Mg(NO3)2·6H2O, and CaCl2·2H2O are prepared at metal salt molar fractions ranging from 0.10 to 0.35. Density, viscosity, speed of sound, surface tension, and contact angle are measured over the temperature range of 293.15–343.15 K at atmospheric pressure. Experimental density, viscosity, and speed-of-sound data were correlated using empirical regression models, providing accurate descriptions of their temperature dependence and enabling predictive capability. Surface tension and contact angle measurements are used to assess interfacial behavior and wettability, revealing clear dependencies on DES composition and substrate nature. Overall, this work provides a consistent data set of bulk and interfacial properties for these choline chloride:glycerol:metal salt hydrated DES systems, contributing to improved structure–property understanding and supporting their rational design and application in process-oriented systems.
PB ACS Publications
SN 0021-9568
YR 2026
FD 2026-07
LK https://hdl.handle.net/10259/12015
UL https://hdl.handle.net/10259/12015
LA eng
DS Repositorio Institucional de la Universidad de Burgos
RD 07-sep-2026