RT info:eu-repo/semantics/article
T1 Gold(I)-catalyzed 6-endo hydroxycyclization of 7-substituted-1,6-enynes
A1 Sanjuán Cortázar, Ana María
A1 Martínez Cuezva, Alberto
A1 García García, Patricia
A1 Fernández Rodríguez, Manuel A.
A1 Sanz Díez, Roberto
K1 catalysis
K1 dihydronaphthalenes
K1 gold
K1 gold catalysis
K1 hydroxycyclization
K1 selectivity
K1 Química orgánica
K1 Chemistry, Organic
AB The cyclization of o-(alkynyl)-3-(methylbut-2-enyl)benzenes, 1,6-enynes having a condensed aromatic ring at C3–C4 positions, hasbeen studied under the catalysis of cationic gold(I) complexes. The selective 6-endo-dig mode of cyclization observed for the7-substituted substrates in the presence of water or methanol giving rise to hydroxy(methoxy)-functionalized dihydronaphthalenederivatives is highly remarkable in the context of the observed reaction pathways for the cycloisomerizations of 1,6-enynes bearinga trisubstituted olefin
PB Beilstein-Institut
SN 1860-5397
YR 2013
FD 2013-10
LK http://hdl.handle.net/10259/3800
UL http://hdl.handle.net/10259/3800
LA eng
NO Ministerio de Ciencia e Innovación (MICINN) and FEDER (CTQ2010-15358)
DS Repositorio Institucional de la Universidad de Burgos
RD 23-nov-2024