RT info:eu-repo/semantics/article
T1 An unprecedented use for glycerol: chemoselective reducing agent for sulfoxides
A1 García Bartolomé, Nuria
A1 García García, Patricia
A1 Fernández Rodríguez, Manuel A.
A1 García, Daniel
A1 Pedrosa Sáez, María de los Remedios
A1 Arnáiz García, Francisco Javier
A1 Sanz Díez, Roberto
K1 Química orgánica
K1 Chemistry, Organic
AB A new application for glycerol that expands its possibilities beyond a green solvent and a precursor ofvalue-added products has been demonstrated. Simple, easily available, and environmentally friendly dioxomolybdenum(VI) complexes are highly efficient catalysts for the chemoselective sulfoxide deoxygenationwith this biomass-derived chemical feedstock. Both refined glycerol and crude glycerin can be used, thusexpanding the potential application of this reaction. Subsequent transformation of glycerol during thisreductive process has also been investigated
PB Royal Society of Chemistry
YR 2013
FD 2013-02
LK http://hdl.handle.net/10259/3802
UL http://hdl.handle.net/10259/3802
LA eng
NO Ministerio de Ciencia e Innovacion (MICINN), FEDER (CTQ2010-15358 and CTQ2009-09949/BQU), Junta de Castilla y Leon (BU021A09 and GR-172), MICINN ("Juan de la Cierva" and "Ramon y Cajal" contracts for P.G.-G. and M.A.F.-R.)
DS Repositorio Institucional de la Universidad de Burgos
RD 20-abr-2024