RT info:eu-repo/semantics/article
T1 Pinacol as a new green reducing agent: molybdenum-catalyzed chemoselective reduction of sulfoxides and nitroaromatics
A1 García Bartolomé, Nuria
A1 García García, Patricia
A1 Fernández Rodríguez, Manuel A.
A1 Rubio Presa, Rubén
A1 Pedrosa Sáez, María de los Remedios
A1 Arnáiz García, Francisco Javier
A1 Sanz Díez, Roberto
K1 chemoselectivity
K1 molybdenum
K1 nitro compounds
K1 reduction
K1 sulfoxides
K1 Química orgánica
K1 Chemistry, Organic
AB Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions
PB Wiley-VCH Verlag
SN 1615-4150
YR 2012
FD 2012-02
LK http://hdl.handle.net/10259/3890
UL http://hdl.handle.net/10259/3890
LA eng
NO Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021 A09 and GR-172) for financial support. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts
DS Repositorio Institucional de la Universidad de Burgos
RD 23-abr-2024