RT info:eu-repo/semantics/article
T1 Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes
A1 Sanjuán Cortázar, Ana María
A1 García García, Patricia
A1 Fernández Rodríguez, Manuel A.
A1 Sanz Díez, Roberto
K1 cycloisomerization
K1 cyclopentadienes
K1 Diels–Alder reaction
K1 dienynes
K1 gold
K1 Química orgánica
K1 Chemistry, Organic
AB An asymmetric synthesis of elusive chiral cyclopentadienes has been developed by gold(I)-catalyzed alkoxycyclization of 1,3-dien-5-ynes. The application of these substrates in completely diastereoselective Diels–Alder cycloaddition reactions, which can be carried out in one pot from achiral 1,3-dien-5-ynes, allows the preparation of highly functionalized products bearing five stereogenic centers with high enantiomeric excesses
PB Wiley-VCH Verlag
SN 1615-4150
YR 2013
FD 2013-07
LK http://hdl.handle.net/10259/3893
UL http://hdl.handle.net/10259/3893
LA eng
NO Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial support. A. M. S. thanks Junta de Castilla y Leon (Consejeria de Educacion) and Fondo Social Europeo for a PIRTU contract. P. G.-G. and M. A. F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts
DS Repositorio Institucional de la Universidad de Burgos
RD 22-nov-2024