RT info:eu-repo/semantics/article T1 1,3-Dien-5-ynes: Versatile Building Blocks for the Synthesis of Carbo- and Heterocycles A1 Aguilar, Enrique A1 Sanz Díez, Roberto A1 Fernández Rodríguez, Manuel A. A1 García García, Patricia K1 Chemistry, Organic K1 Química orgánica AB 1,3-Dien-5-ynes have been extensively used as starting materials for thesynthesis of a wide number of different carbo- and heterocycles. The aim of this review isto give an overview of their utility in organic synthesis, highlighting the variety ofcompounds that can be directly accessed from single reactions over these systems. Thus,cycloaromatization processes are initially commented, followed by reactions directedtoward the syntheses of five-membered rings, other carbocycles and, finally, heterocycles.The diverse methodologies that have been developed for the synthesis of each of thesetypes of compounds from 1,3-dien-5-ynes are presented, emphasizing the influence ofthe reaction conditions and the use of additional reagents in the outcome of thetransformations. PB American Chemical Society SN 0009-2665 YR 2016 FD 2016-07 LK http://hdl.handle.net/10259/4274 UL http://hdl.handle.net/10259/4274 LA eng NO Ministerio de Economíay Competitividad(MINECO) and FEDER (CTQ2013-41336-P, CTQ2013-48937-C2-1-P, and CTQ2014-52488-R), Universidad de Alcalá(CCG2015/EXP-003) and Junta de Castilla y León(BU237U13) DS Repositorio Institucional de la Universidad de Burgos RD 24-nov-2024