RT info:eu-repo/semantics/article
T1 Formal [4 + 1] Cycloadditions of β,β-Diaryl-Substituted ortho-(Alkynyl)styrenes through Gold(I)-Catalyzed Cycloisomerization Reactions
A1 Sanjuán Cortázar, Ana María
A1 Virumbrales Ortiz, Cintia
A1 García García, Patricia
A1 Fernández Rodríguez, Manuel A.
A1 Sanz Díez, Roberto
K1 Chemistry, Organic
K1 Química orgánica
AB Gold(I)-catalyzed cycloisomerization of β,β-diaryl-o-(alkynyl)-styrenes at 80 °C selectively yields dihydroindeno[2,1-a]indenes in atransformation that encompasses a formal [4 + 1] cycloaddition and takesplace through a cascade 5-endo-cyclization−diene activation−iso-Nazarovcyclization. In addition, by performing the reaction at 0 °C, the samesubstrates exclusively give rise to benzofulvene derivatives, which have also been shown to be intermediates in the formation ofthe tetracyclics.
PB American Chemical Society
SN 1523-7060
YR 2016
FD 2016-03
LK http://hdl.handle.net/10259/4275
UL http://hdl.handle.net/10259/4275
LA eng
NO Junta de Castilla y León (BU237U13)and Ministerio de Economıá y Competitividad (MINECO) andFEDER (CTQ2013-48937-C2-1-P)
DS Repositorio Institucional de la Universidad de Burgos
RD 23-nov-2024