RT info:eu-repo/semantics/article
T1 A Selective, Efficient and Environmentally Friendly Method for the Oxidative Cleavage of Glycols
A1 García Bartolomé, Nuria
A1 Rubio Presa, Rubén
A1 García García, Patricia
A1 Fernández Rodríguez, Manuel A.
A1 Pedrosa Sáez, María de los Remedios
A1 Arnáiz García, Francisco Javier
A1 Sanz Díez, Roberto
K1 Química orgánica
K1 Chemistry, Organic
AB A catalytic methodology for the oxidative cleavage of vicinal diols is described as an advantageous alternative in terms of the environmental impact on classical methods involving toxic oxidants. The novel strategy is based on the use of dioxomolybdenum(VI) complexes as catalysts and dimethyl sulfoxide (DMSO) as an oxidant and displays high selectivity and a broad scope for glycol cleavage. In addition, the developed system is also useful for the oxidation of acyloins to diketones.
PB Royal Society of Chemistry
SN 1463-9262
YR 2016
FD 2016-04
LK http://hdl.handle.net/10259/4289
UL http://hdl.handle.net/10259/4289
LA eng
NO Ministerio de Economía y Competitividad(MINECO) and FEDER (CTQ2013-48937-C2-1-P) and Juntade Castilla y León (BU237U13)
DS Repositorio Institucional de la Universidad de Burgos
RD 22-dic-2024