RT info:eu-repo/semantics/article
T1 Liquid–liquid equilibria for systems glycerol + sardine oil + tert-alcohols
A1 García Solaesa, Ángela
A1 Bucio López, Silvia Liliana
A1 Sanz Díez, Mª Teresa
A1 Beltrán Calvo, Sagrario
A1 Rebolleda Alonso, Sara
K1 Liquid–liquid equilibria
K1 Fish oil
K1 Glycerolysis
K1 Tertiary alcohols
K1 Chemical engineering
K1 Ingeniería química
AB Monoacylglycerols (MAGs) can be produced by lipase-catalyzed glycerolysis of oils and fats at atmospheric pressure and low temperature. The use of organic solvents as reaction media helps to create a homogeneous reaction system between the immiscible reactants glycerol and oil. In this work liquid–liquid equilibrium at two different temperatures (303.2 and 323.2 K) and at atmospheric pressure has been determined for two solvent-systems in the glycerolysis of fish oil (sardine oil): glycerol + sardine oil + tert-butanol and glycerol + sardine oil + tert-pentanol. From the experimental solubility (binodal) curves and tie-lines, it could be observed that the system mutual solubility does not significantly increase by increasing temperature from 303.2 to 323.2 K. The Othmer–Tobias correlation was used to analyze the consistency of the tie-line data. The experimental liquid–liquid data were correlated satisfactorily by using the NRTL model for the activity coefficient calculation.
PB Elsevier
SN 0378-3812
YR 2013
FD 2013-10
LK http://hdl.handle.net/10259/4336
UL http://hdl.handle.net/10259/4336
LA eng
NO MINECO (CTQ2012-39131-C02-01) and CDTI (Ref. IDI-20111225)
DS Repositorio Institucional de la Universidad de Burgos
RD 23-nov-2024