RT info:eu-repo/semantics/article
T1 Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent
A1 Rubio Presa, Rubén
A1 Fernández Rodríguez, Manuel A.
A1 Pedrosa Sáez, María de los Remedios
A1 Arnáiz García, Francisco Javier
A1 Sanz Díez, Roberto
K1 amine N-oxides
K1 deoxygenation
K1 molyb-denum
K1 microwave heating
K1 N-hydroxybenzotria-zoles
K1 Química orgánica
K1 Chemistry, Organic
AB A molybdenum-catalyzed deoxygenationof pyridine N -oxides and N-hydroxybenzotriazoles,as well as other azole N-oxides, has been developedusing pinacol as an environmentally friendly oxo-acceptor. The only by-products are acetone andwater making the process a convenient alternativeto established protocols in terms of waste gener-ation. The reaction is highly chemose lective and avariety of functional groups are tolerated. Theprocesses are usually very clean allowing theisolation of the pure deoxygenated products after asimple extraction in most cases.
PB Wiley-VCH Verlag
SN 1615-4150
YR 2017
FD 2017-05
LK http://hdl.handle.net/10259/4528
UL http://hdl.handle.net/10259/4528
LA eng
NO Ministerio de Economı´ayCompetitividad (MINECO) (CTQ2013-48937-C2-1-P,CTQ2015-70371-REDT, and CTQ2016-75023-C2-1-P) andJunta de Castilla y Leo´n and FEDER (BU076U16)
DS Repositorio Institucional de la Universidad de Burgos
RD 03-dic-2024